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Fructose has a higher impact on freezing level depression than disaccharides or oligosaccharides, which can protect the integrity of cell walls of fruit by lowering ice crystal formation. Fructose is a 6-carbon polyhydroxyketone. High-fructose corn syrup is a mixture of glucose and fructose as monosaccharides. Because fructose exists to a higher extent within the open-chain form than does glucose, the preliminary phases of the Maillard reaction happen more rapidly than with glucose. In answer, fructose exists as an equilibrium mixture of the tautomers β-d-fructopyranose, β-d-fructofuranose, α-d-fructofuranose, α-d-fructopyranose and keto-d-fructose (the non-cyclic form). Fructose exists in foods either as a free monosaccharide or bound to glucose as sucrose, a disaccharide. Fructose, glucose, and sucrose might all be current in meals; nevertheless, totally different foods will have varying ranges of every of those three sugars. 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